Browse by Subject "Chemistry, Organic"
Now showing items 779-782 of 782
Use of the Cyclopropylcarbinyl - Allylcarbinyl Rearrangement as a Probe of the Thiophilic Addition Reaction Mechanism (1985)The mechanism of thiophilic addition was examined using the reported ring opening rearrangements of cyclopropylcarbinyl species as a probe to determine whether the reaction proceeds in a one or two electron fashion. A ...
The Utility of 7-Deazaguanine: Part I. High Affinity, High Fidelity Modules for Supramolecular Chemistry, And, Part II. Molecular Recognition of Uracil and Thymine (2007)A water-soluble analogue of the 2-naphthyl-7-DeG host was synthesized and evaluated as a molecular recognition unit to a thymine (T) bulge of a short 10-bp oligomer. The ligand was found to stabilize the T bulge quite ...
Utilization of Rationally Designed Small Molecule Chiral Selectors in Novel Enantioselective Processes (2003)In addition, phase transfer catalyzed biphasic kinetic resolutions of several racemic amides containing electron-deficient aromatic moieties are described. The method revolves around forming Meisenheimer adducts which are ...