Browse by Subject "amination"
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Development and mechanistic investigation of the palladium-catalyzed α-arylation of aldehydes and N-arylation of ammonia (2011-01-21)A general method for the palladium-catalyzed α-arylation of aldehydes was developed to couple linear and branched aldehydes with electron-poor and electron-rich bromo- and chloroarenes in high yields. Catalysts generated ...
Mechanisms of multielectron redox catalysis with low-valent cobalt: defining the roles of coordination number, stereoelectronics and field effects in selectivity for two-electron chemistry (2015-10-22)Employing first-row transition metals in catalytic two-electron transformations remains a synthetic challenge. In order to overcome the common and often deleterious single-electron reactivity, an electron rich ligand was ...
(2012-06-27)The reductive eliminations of primary arylamines from a series of bisphosphine-ligated arylpalladium(II) parent amido complexes countered several established trends. In contrast to arylamido and alkylamido complexes of the ...