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 Title: INELASTIC COLLISIONS OF Ar AND O3 Author(s): Sur, Sangeeta Contributor(s): Dawes, Richard; Ndengue, Steve Alexandre; Quintas Sánchez, Ernesto Subject(s): Electronic structure, potential energy surfaces Abstract: \begin{wrapfigure}{r}{0pt} \includegraphics[scale=0.62]{new-fig.eps} \end{wrapfigure} According to the Chapman cycle, during formation, metastable ozone can be stabilized by a third body (M) collision (buffer gas) in the atmosphere. The stabilization occurs through an energy transfer (ET) mechanism from O$_3^*$ to M. The details of this ET are not well known and one of the reasons is the lack of an accurate potential energy surface (PES) including the collision partner. The PES of the O$_3$-Ar complex is a 6D problem in full-dimensionality, or 3D for rigid O$_3$. Here we present a global 3D PES for O$_3$ fixed at equilibrium, interacting with Ar. Highly accurate Davidson-corrected multi-reference configuration interaction (MRCI-f12) energies were computed at 2112 data points. The AUTOSURF code was used to construct the PES automatically, represented by a local interpolating moving least-squares (L-IMLS) method. A global RMS fitting error of 0.6~cm$^{-1}$ was obtained. Symmetry equivalent minima with a well depth of -229~cm$^{-1}$ are located above and below the plane of O$_3$. We present here bound vdW states of the O$_3$-Ar complex obtained by variational rovibrational calculations, as well as quantum scattering cross-sections for rotationally inelastic collisions. Issue Date: 06/21/18 Publisher: International Symposium on Molecular Spectroscopy Citation Info: APS Genre: Conference Paper / Presentation Type: Text Language: English URI: http://hdl.handle.net/2142/100539 DOI: 10.15278/isms.2018.RJ05 Other Identifier(s): RJ05 Date Available in IDEALS: 2018-08-172018-12-12
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