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Title:MICROWAVE STUDY OF 2-PHENYLPYRIDINE AND THEIR WATER COMPLEXES
Author(s):Blanco, Susana
Contributor(s):Lopez, Juan Carlos; Macario, Alberto
Subject(s):Clusters/Complexes
Abstract:2-Phenylpyridine (2pp) is well known as an organic ligand in metal complexes, systems which present a relevant importance in fields such as inorganic photochemistry, biological electron-transfer dynamics or, for example, as chromophores in semiconductor assemblies in solar energy panels. The analysis of the rotational spectra of the parent and all the $^{13}$C and $^{15}$N isotopologues for the 2pp, split by the torsional vibration, have allowed us to determine the structure of 2pp. Furthermore, it has been possible to detect the spectra of the 1:1 and 1:2 water complexes. For the 1:1 adduct, the spectra of the parent and the same isotopologues as observed for the monomer have been measured. This has enabled direct structural comparison between the bare molecule and its water complex, determining how the water affects the structure of 2pp.
Issue Date:06/21/18
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:APS
Genre:Conference Paper / Presentation
Type:Text
Language:English
URI:http://hdl.handle.net/2142/100668
DOI:10.15278/isms.2018.RK05
Other Identifier(s):RK05
Date Available in IDEALS:2018-08-17
2018-12-12


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