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Title:THE CONFORMER SPECIFIC ROOM-TEMPERATURE ROTATIONAL SPECTRUM OF ALLYL CHLORIDE UTILIZING STRONG FIELD COHERENCE BREAKING
Author(s):Riffe, Erika
Contributor(s):Zwier, Timothy S.; Hernandez-Castillo, Alicia O.; Fritz, Sean; Shipman, Steven; Johnson, Erika
Subject(s):Instrument/Technique Demonstration
Abstract:The 8-26.5 GHz conformer specific rotational spectrum of allyl chloride was recorded in a room temperature spectrometer using the strong field coherence breaking (SFCB) technique.\footnote{Hernandez-Castillo, A.O., Abeysekera, C., Hays, B.M., Zwier, T.S. “Broadband Multi-Resonant Strong Field Coherence Breaking as a Tool for Single Isomer Microwave Spectroscopy.” J. Chem. Phys. 145, 114203 (2016).} Allyl chloride, which has \textit{cis}- and \textit{skew}- conformers as well as $^{35}$Cl and $^{37}$Cl isotopologues, was chosen as the initial molecule for testing this method in the room temperature chirped pulse waveguide setup.\footnote{Reinhold, B., Finneran, I.A., Shipman, S.T. “Room temperature chirped-pulse Fourier transform microwave spectroscopy of anisole.” J. Mol. Spec. 270, 89 (2011).} This data was compared to results from the SFCB technique performed at Purdue University using a jet expansion at 1-2K. The application of this and other methods for the simplification of room temperature spectra will be discussed.
Issue Date:06/19/18
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:APS
Genre:Conference Paper / Presentation
Type:Text
Language:English
URI:http://hdl.handle.net/2142/100712
DOI:10.15278/isms.2018.TI11
Other Identifier(s):TI11
Date Available in IDEALS:2018-08-17
2018-12-12


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