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Title:STRUCTURE DETERMINATION OF 5 MEMBERED SILANE RINGS USING MICROWAVE SPECTROSCOPY
Author(s):Marshall, Frank E.
Contributor(s):Grubbs II, G. S.; Guirgis, Gamil A.; Carrigan-Broda, Theodore; Jones, Grier; Sedlacek, Ivan; Gillcrist, David Joseph; Moon, Nicole; Duerden, Amanda Jo
Subject(s):Rotational structure/frequencies
Abstract:Rotational spectra of 1,1-difluorosilacyclopent-3-ene, silacyclopent-3-ene, 1-(chloromethyl)-1-fluoro-silacyclopentane, 1,1-difluorosilacyclopentane, and 1,1-difluorosilacylopent-2-ene were observed in the 6 to 18 GHz range of the electromagnetic spectrum. The molecular structure for the parent and various isotopically substituted species were obtained from their respective spectra. The differences in structure between these similar molecules will be presented, showing how different functional groups and bond locations affect the overall structure and behavior of each system (ring puckering effects, etc.). Comparisons to similar known cyclopentane and silacyclopentane species will be presented.
Issue Date:06/19/18
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:APS
Genre:Conference Paper / Presentation
Type:Text
Language:English
URI:http://hdl.handle.net/2142/100766
DOI:10.15278/isms.2018.TJ10
Other Identifier(s):TJ10
Date Available in IDEALS:2018-08-17
2018-12-12


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