Files in this item

FilesDescriptionFormat

application/pdf

application/pdf1083751.pdf (9MB)
PresentationPDF

application/pdf

application/pdf2953.pdf (22kB)
AbstractPDF

Description

Title:LINE INTENSITY MEASUREMENTS AND ANALYSIS IN THE ν3 BAND OF RUTHENIUM TETROXIDE
Author(s):Vander Auwera, Jean
Contributor(s):Manceron, Laurent; Doizi, Denis; Boudon, Vincent; Reymond-Laruinaz, Sébastien
Subject(s):Small molecules
Abstract:Ruthenium tetroxide (RuO$_4$) is a heavy tetrahedral molecule characterized by an unusual volatility near ambient temperature. Because of its chemical toxicity and the radiological impact of its $^{103}$Ru and $^{106}$Ru isotopologues, the possible remote sensing of this compound in the atmosphere has renewed interest in its spectroscopic properties. In a recent study, the strong fundamental band associated with the excitation of the infrared active stretching mode $\nu_3$ of $^{102}$Ru$^{16}$O$_4$, observed near 10 $\mu$m, was re-investigated at high-resolution (0.001 cm$^{-1}$) with the help of a $^{102}$Ru isotopically pure sample.\footnote{S. Reymond-Laruinaz, V. Boudon, L. Manceron, L. Lago, D. Doizi, J Mol Spectrosc 315 (2015) 46--54.} Building upon that work, the present contribution is the first investigation dealing with high-resolution line-by-line intensity measurements for the $\nu_3$ fundamental band of $^{102}$Ru$^{16}$O$_4$. It relies on high resolution Fourier transform infrared spectra specifically recorded at room temperature at the AILES beam line of SOLEIL using synchrotron radiation, a specially constructed cell and an isotopically pure sample of $^{102}$Ru$^{16}$O$_4$. Relying on an effective Hamiltonian and associated effective dipole moment,$^{a}$ the measured line intensities were assigned and dipole moment parameters determined. A HITRAN-formatted frequency and intensity line list was generated.
Issue Date:06/20/18
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:APS
Genre:Conference Paper / Presentation
Type:Text
Language:English
URI:http://hdl.handle.net/2142/100786
DOI:10.15278/isms.2018.WH08
Other Identifier(s):WH08
Date Available in IDEALS:2018-08-17
2018-12-12


This item appears in the following Collection(s)

Item Statistics