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Title:BOND INSERTION IN METAL–CARBON DIOXIDE ANIONIC CLUSTERS STUDIED BY INFRARED PHOTODISSOCIATION SPECTROSCOPY
Author(s):Dodson, Leah G.
Contributor(s):Weber, J. Mathias; Thompson, Michael C.
Subject(s):Plenary
Abstract:C–O bond breaking is an important process in the activation of \chem{CO_2} that can be catalyzed by the presence of a metal. In this talk, we investigate the factors that lead to bond insertion in [M(\chem{CO_2})$_{y}$]$^{-}$ gas phase clusters, specifically addressing differences amongst the metals M = Ni, Fe, and Ti. Gas phase anionic clusters were generated using laser ablation of a metal target in the presence of a \chem{CO_2} expansion, and the infrared photodissociation spectra were measured from 950–2400 \wn. Metal carbonyl vibrational signatures were used to infer bond insertion, and computational chemistry simulations were used to assess the feasibility of bond breaking in these systems.
Issue Date:06/21/18
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:APS
Genre:Conference Paper / Presentation
Type:Text
Language:English
URI:http://hdl.handle.net/2142/100834
DOI:10.15278/isms.2018.RA03
Other Identifier(s):RA03
Date Available in IDEALS:2018-08-17
2018-12-12


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