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Title:AROMATICITY IN METALLABORON CLUSTERS
Author(s):Kocheril, G. Stephen
Contributor(s):Wang, Lai-Sheng ; Czekner, Joseph ; Cheung, Ling Fung
Subject(s):Clusters/Complexes
Abstract:Metallabenzenes are a class of molecules in which a CH unit in benzene is replaced by a functionalized transition metal atom. While all-boron analogues of aromatic and antiaromatic hydrocarbons are well-known, there have not been any metallaboron analogs using high-resolution photoelectron imaging and quantum chemical calculations. Vibrationally resolved photoelectron spectra have been obtained and compared with theoretical results, determining their structures. Through chemical bonding analyses, we have identified unique aromatic characters in these metallaboron clusters.
Issue Date:23-Jun-20
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:APS
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/107702
Date Available in IDEALS:2020-06-26


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