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Title:Rheology-Chemical Based Procedure to Evaluate Additives/Modifiers Used in Asphalt Binders for Performance Enhancements: Phase 2
Author(s):Singhvi, Punit; García Mainieri, Javier J.; Ozer, Hasan; Sharma, Brajendra
Subject(s):Softener-type Modifiers
Bio-based Modifiers
Long-term Field Aging
Asphalt Rheology
Asphalt Chemistry
I-FIT
Hamburg Wheel-track Test
Glover-Rowe Parameters
Viscoelastic Transition Temperature
Black Angle
FTIR
GPC
Abstract:The increased use of softer binders in Illinois over the past decade is primarily attributed to the increased use of recycled materials in asphalt pavement construction. The shift in demand of using PG 58-28 over PG 64-22 has resulted in potential alternative methods to produce softer binders more economically using proprietary products. However, there are challenges in using these proprietary products for asphalt modification because of uncertainty in their long-term performance and significant variability in binder chemistry. The current SuperPave performance grading specification for asphalt binders is insufficient in differentiating binders produced from these modifiers. Therefore, the objective of this study is to evaluate the performance of various softener-type asphalt binder modifiers using a wide array of rheological and chemistry tests for their integration into the Illinois Department of Transportation’s material specifications. The small-strain rheological tests and their parameters allowed for consistent grouping of modified binders and can be used as surrogates to identify performing and nonperforming asphalt binders. A new parameter, Δ|G*|peak τ, was developed from the linear amplitude sweep test and showed potential to discriminate binders based on their large-strain behavior. Chemistry-based parameters were shown to track aging and formulation changes. The modifier sources were identified using fingerprint testing and were manifested in the modified binder chemical and compositional characteristics. The two sources of base binders blended with the modifiers governed the aging rate of the modified binders. Mixture performance testing using the Illinois Flexibility Index Test and the Hamburg Wheel-Track Test were consistent with the rheological and chemical findings, except for the glycol amine-based modified binder, which showed the worst cracking performance with the lowest flexibility index among the studied modifiers. This was contrary to its superior rheological performance, which may be attributed to lower thermal stability, resulting in high mass loss during mixing. According to the characterization of field-aged binders, laboratory aging of two pressurized aging vessel cycles or more may represent realistic field aging of 10 to 15 years at the pavement surface and is able to distinguish modified binders. Therefore, an extended aging method of two pressurized aging vessel cycles was recommended for modified binders. Two different testing suites were recommended for product approval protocol with preliminary thresholds for acceptable performance validated with field-aged data.
Issue Date:2021-06
Publisher:Illinois Center for Transportation/Illinois Department of Transportation
Citation Info:Singhvi, Punit, Javier J. García Mainieri, Hasan Ozer, and Brajendra K. Sharma. 2021. Rheology-Chemical Based Procedure to Evaluate Additives/Modifiers Used in Asphalt Binders for Performance Enhancements: Phase 2. A report of the findings of ICT-R27-196-HS. Illinois Center for Transportation Series No. 21-020. Research Report No. FHWA-ICT-21-015. Illinois Center for Transportation, Rantoul, IL. https://doi.org/10.36501/0197-9191/21-020
Series/Report:FHWA-ICT-21-015
Genre:Technical Report
Type:Text
Language:English
URI:http://hdl.handle.net/2142/110079
ISSN:0197-9191
DOI:https://doi.org/10.36501/0197-9191/21-020
Sponsor:IDOT-ICT-196-HS
Rights Information:No restrictions. This document is available through the National Technical Information Service, Springfield, VA 22161.
Date Available in IDEALS:2021-06-22


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