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Browse Abstracts & Presentations - 2021 International Symposium on Molecular Spectroscopy by Subject "Radicals"
Now showing items 1-14 of 14
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(International Symposium on Molecular Spectroscopy, 2021-06-23)Nitrogen-substituted polycyclic aromatic hydrocarbons (PANHs) are fundamental species important in biological molecules, astrochemistry, and combustion. They have been detected on meteorites with non-terrestrial isotopic ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)A decade ago, the advent of broadband chirped-pulse Fourier-transform microwave spectrometers revolutionized rotational spectroscopy in the centimeter-wave region [1]. Commercial solution are available in the millimeter-wave ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)A wide variety of nitrogen-containing heterocycles have been detected on meteorites with non-terrestrial isotopic abundances, indicative of an interstellar origin. However, no N-heterocycles have been detected in space and ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)The electronic spectra of the resonance-stabilized radical C$_9$H$_9$ isomers \textit{cis}- and \textit{trans-meta}-vinylbenzyl (MVB), generated in a supersonically cooled discharge of \textit{m}-vinyltoluene, have been ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)The copper hydroxide ion, CuOH+ , serves as the catalytic core in several recently developed water-splitting catalysts, and an understanding of its chemistry is critical to determining viable catalytic mechanisms. In spite ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)Calcium monohydride CaH is found in the Sun and other stars. Indeed, its A-X electronic spectrum has been a useful probe for stellar classification.\footnote{For example, J.E. Gizis, \textit{Astron. J.} \underline{\textbf{113}}, ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)High-resolution anion photoelectron spectra of cryogenically cooled Si$_3$C$^{-}$, Si$_2$C$^{-}_2$, and SiC$^{-}_3$ obtained using slow photoelectron velocity-map imaging (cryo-SEVI) are presented, providing insight into ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)First high-resolution mid infrared rovibrational spectral data on jet cooled bromocarbene (HCBr) diradical are obtained using quantum shot noise limited laser absorption methods. The HCBr diradical is generated by coflowing ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)Methyl vinyl ketone oxide [MVKO, C$_{2}$H$_{3}$C(CH$_{3}$)OO], an important Criegee intermediate in ozonolysis of isoprene, was recently identified in laboratories with near infrared action spectrum (to produce OH) using ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)The addition reactions of iodine atom with propene in solid para-hydrogen (p-H$_{2}$) matrices were investigated with infrared (IR) absorption spectroscopy. Mixtures of propene and I$_{2}$ seeded in p-H$_{2}$ were co-deposited ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)The reduced reactivity of resonance-stabilized hydrocarbon radicals allows for them to reach higher concentrations in harsh environments such as flames or planetary atmospheres. Reactions between them remain rapid and could ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)Glycolaldehyde (HOCH$_2$CHO) has been detected in the interstellar medium; it is considered to play an important role in the formation of complex organic molecules, especially higher sugars. We took the advantages of unique ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)Aromatic oxide free radicals play an important role in atmospheric and combustion chemistry, where they are involved in the formation of secondary organic aerosols and soot. The oxygen atom lone pairs can readily mix with ...
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(International Symposium on Molecular Spectroscopy, 2021-06-23)We are currently studying the $\tilde{B}$ $^2E'$ -- $\tilde{X}$ $^2A_2'$ system of jet cooled NO$_3$ via laser induced fluorescence (~LIF~) spectroscopy. The dispersed fluorescence (~DF~) spectrum from the vibrationless ...
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Now showing items 1-14 of 14