Files in this item

FilesDescriptionFormat

application/pdf

application/pdf5642.pdf (14kB)
(no description provided)PDF

Description

Title:The Microwave Spectrum And Molecular Structure Of trans-2-fluoro-3-(trifluoromethyl)oxirane And Its Complex With The Argon Atom
Author(s):Aucoin, Jordan M.
Contributor(s):Marshall, Mark D.; Leung, Helen O.
Subject(s):Structure determination
Abstract:Structurally similar to previously characterized chiral tagging candidates, {\it trans}-2-fluoro-3-(trifluoromethyl)oxirane (tFTFO) is investigated, both theoretically and experimentally, as a potential chiral tagging molecule. With a strong, simple rotational spectrum, tFTFO shows promise for applications in chiral analysis through the conversion of enantiomers into spectroscopically distinct diastereomeric species through noncovalent attachment. Fourier transform microwave spectroscopy from 5.6 to 18.1 GHz is used to obtain the rotational spectrum of five isotopologues of tFTFO and four isotopologues of its heterodimer with the argon atom. Analysis of these spectra allows the determination of the structures for both species. Initial results show that the structure of the argon complex is distinct from the structures previously described for the 3,3,3-trifluoro-, 3,3-difluoro-, and 3-fluoro-1,2-epoxypropane species, suggesting that the addition of the fluorine atom to the ring carbon alters bonding in the epoxy moiety.
Issue Date:2021-06-24
Publisher:International Symposium on Molecular Spectroscopy
Genre:Conference Paper / Presentation
Type:Text
Language:English
URI:http://hdl.handle.net/2142/111456
Date Available in IDEALS:2021-09-24


This item appears in the following Collection(s)

Item Statistics