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Title:In Search Of Vibrationally Excited State Monodromy In Ncncs
Author(s):Tokaryk, Dennis W.
Contributor(s):Billinghurst, Brant E.; De Lucia, Frank C.; Winnewisser, Brenda P.; Winnewisser, Manfred; Ross, Stephen Cary
Subject(s):Mini-symposium: Large Amplitude Motions
Abstract:At previous ISMS meetings we have reported on the effects of monodromy on the $\nu_7$ bending mode of NCNCS. The presence of monodromy was established directly from experimental data collected at the Canadian Light Source. To aid that work we assigned some of the spectrum of the $\nu_7$ manifold built on the $\nu_3$ stretching mode. In this talk we will discuss a more complete assignment of the $\nu_3$+$\nu_7$ spectrum. One of our goals is to consider the impact of stretching on the monodromy of the $\nu_7$ mode. We will attempt to use the same Generalized SemiRigid Bender model as was applied to the pure $\nu_7$ mode.
Issue Date:2021-06-24
Publisher:International Symposium on Molecular Spectroscopy
Genre:Conference Paper / Presentation
Date Available in IDEALS:2021-09-24

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