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Browse Dissertations and Theses - Chemistry by Title
Now showing items 516-535 of 2941
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(2019-03-29)Aromatic compounds represent one of the most abundant classes of organic molecules, and are suitable precursors for synthesizing functionalized alicyclic hydrocarbon frameworks. Accordingly, many unique and enabling ...
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(2021-06-21)Anthracyclines are archetypal representatives of tetracyclic type II polyketide natural products that are widely used in cancer chemotherapy. Although syntheses of this class of compounds have been extensively explored, ...
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(2017-04-27)A novel method for the dearomative reduction of arenes through the use of N,N-arenophile, MTAD, was developed. Cheap feedstock arenes undergo photocycloaddition with MTAD, and the cycloadduct can be treated further to ...
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(2019-02-19)Dearomatization reactions represent a powerful tool for the conversion of readily-available arenes into structurally complex, high-value intermediates in synthesis. Although there are many classic and modern approaches for ...
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(2004)A new soft-lithographic method for micropatterning polymeric resists, Decal Transfer Lithography (DTL), is described. This technique is based on the adhesive transfer of elastomeric decal patterns via the engineered adhesion ...
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(1981)The development of methodology for the regioselective synthesis of tetra-beta-substituted naphthalenes via a combination of bicyclo{4.2.0}octa-1,3,5-triene and aryl trimethylsilyl chemistry led to the synthesis of ...
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(1980)Pyrazolo{4,3-g}quinazolin-5-one (lin-benzoallopurinol), an extended analogue of 4-hydroxypyrazolo{3,4-d}pyrimidine (allopurinol), and pyrazolo{3,4-f}quinazolin-9-one (proxbenzoisoallopurinol), an extended analogue of ...
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(1963)
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(2015-09-23)Cancer and antibiotic-resistant bacterial infections are currently two of the major health concerns facing the United States. Novel therapeutics capable of specifically targeting either cancer or resistant bacteria are ...
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(2012-02-06)While DNA is most familiar in its double-stranded form as a storehouse of genetic information, its chemical similarities to naturally occurring ribozymes suggest that it can act as a catalyst. Single-stranded DNA molecules ...
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(2005)An ongoing challenge for deoxyribozyme-mediated RNA ligations has been synthesis of native 3'-5' phosphodiester linkages. Previously, reactions of 5'-triphosphate RNA have provided mostly 2',5'-branched RNA. Here we report ...
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(2014-05-30)In nature, the main role of double-stranded DNA is storage of genetic information. However, once a DNA oligonucleotide is freed from its confining complementary strand, it can fold into complex three-dimensional structures ...
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(1983)The orientational relaxation time ((tau)(,LS)) is measured for liquid benzene by depolarized light scattering as a function of temperature and pressure. The values of (tau)(,LS) are compared with the orientational relaxation ...
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(2002)The Si-H bonds on the H-Si(111) surface and Co2(CO)8 in n-heptane solution reacted to form a well defined submonolayer coverage of Co(CO)4 above the surface plane of Si(111). Transmission Fourier-transform infrared ...
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(1988)A novel optical depth profiling technique is developed to depth profile thin optically transparent films which can be fabricated in the form of an asymmetric slab optical waveguide. Various methods for depth profiling thin ...
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Now showing items 516-535 of 2941