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Browse Dissertations and Theses - Chemistry by Title
Now showing items 1009-1028 of 2941
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(1989)A kinetic study of inactivation of $\alpha$-chymotrypsin by enol lactones was performed. Halo enol lactones, 3-(1-naphthyl)-6(E)-(iodomethylene)tetrahydro-2-pyranone ($\alpha$Np6I) and 3-phenyl-6(E)-(bromomethylene)tetra ...
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(1984)Halo enol lactones with a phenyl group situated (beta) or (gamma) to the lactone carbonyl group were prepared to compare their effectiveness as enzyme-activated irreversible (suicide) inhibitors for (alpha)-chymotrypsin ...
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(1985)Halo enol lactones can act as enzyme-activated irreversible inhibitors or suicide substrates for (alpha)-chymotrypsin. Acyl transfer to the active site serine generates a halo methyl ketone that remains tethered in the ...
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(2020-05-04)This dissertation explores surface chemistry of gold nanoparticles, with a special focus in developing analytical methods to decipher the environment of small molecule ligands and biomolecule coronas at the molecular level. ...
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(2017-10-12)A new paradigm for catalyst design through chemoinformatics utilizing quantitative structure activity relationship was investigated. Under this platform, two ‘core’ catalyst scaffolds were chosen. First, Cinchona alkaloids ...
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(2020-07-10)Freshmen and sophomores in college are historically at risk of disengaging with general and organic chemistry courses, performing poorly and not continuing in STEM. Utility value (UV) interventions, though, have increased ...
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(2016-05-20)In recent years, there has been great interest in the synthesis, characterization, and application of gold nanomaterials, especially gold nanorods. Due to their small size, ease of functionalization, and uniquely tunable ...
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(2005)Several different m-phenylene ethynylene (m PE) folding oligomers or foldamers were designed, synthesized, and studied. These chain molecules have been shown to adopt a helical conformation under appropriate conditions in ...
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(1999)In addition, a pyridopyrimidinyl urea was designed to maintain a self-complementary hydrogen-bonding array regardless of its protomeric form. This module was readily synthesized, and 1H NMR studies in a variety of solvents ...
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(2015-07-06)The extracellular matrix is a complex and dynamic collection of collagens, non-collagenous matrix proteins, glycosaminoglycans and growth factors. The ECM plays a significant role in guiding the behavior of cells in their ...
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(2008)To probe the ligand effect, a series of catalyst were prepared by supporting trans-[Re(O)2L4]+ X, (L = pyridine, 4-methylpyridine, 4-methoxypyridine, or 4dimethylaminopyridine, X = Cl - or [ReO4]-) or trans-[ReO 2(L-L)2]I ...
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(1995)When (Re(CO)$\sb3$OH) $\sb4$ was supported on Al$\sb2$O$\sb3$ followed by heating in H$\sb2$ no decomposition gas products, CO and CH$\sb4$, were observed below 650 K. Following the activation by infrared spectroscopy ...
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(1994)Electrochemical studies were performed on two interfacial systems where ions were adsorbed on the electrode surface to form mono- or multi-layer films. The two interfacial systems were glassy carbon/polyoxometallate anion ...
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(2001)Various sequence-specific oligo(m-phenylene ethynylene) foldamers were designed, synthesized and studied. The foldamers were examined with the intention of translating previously reported solution-phase concepts into the ...
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(1987)The reaction of TiCl$\sb4$ with WO$\sb4$((n-C$\sb4$H$\sb9$)$\sb4$N) $\sb2$ in acetonitrile yields ClTiW$\sb5$O$\sb $ ((n-C$\sb4$H$\sb9$)$\sb4$N) $\sb3$. The complexes ROTiW$\sb5$O$\sb $ (n-C$\sb4$H$\sb9$)$\sb4$N) $\sb3$ ...
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Now showing items 1009-1028 of 2941