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Paramagnetic resonance of the F- and M-centers in alkali halides

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Title: Paramagnetic resonance of the F- and M-centers in alkali halides
Author(s): Holton, William Coffeen
Doctoral Committee Chair(s): Slichter, C. P.
Department / Program: Physics
Discipline: Physics
Degree: Ph.D.
Genre: Dissertation
Subject(s): alkali halides
Abstract: A systematic study by electron spin resonance and electron-nuclear double resonance at low temperatures of the F-center in KCl, NaCl, LiCl, NaF, and LiF is reported, together with an inconclusive observation of the M-center resonance by fast passage resonance techniques. A description of the high sensitivity superheterodyne paramagnetic resonance spectrometer used in the investigation is given. The hyper fine coupling of the F-electron to the nearest eight shells of nuclei surrounding the negative ion vacancy has been measured. A root second moment calculated from the measured hyper fine constants is in agreement with experimental slow passage electron spin resonances 0 The discrepancy between theory and experiment in the case of LiF F-centers is resolved g so that the point-ion lattice model theoretical calculations of Gourary and Adrian are in agreement with the experimental results.
Issue Date: 1960
Genre: Dissertation / Thesis
Type: Text
Language: English
Other Identifier(s): 6247243
Publication Status: published or submitted for publication
Rights Information: © 1960 William Coffeen Holton
Date Available in IDEALS: 2010-08-04

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