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Title:High-resolution spectroscopic investigations of rovibrational state mixing in ground electronic states
Author(s):Reid, Scott Allen
Doctoral Committee Chair(s):McDonald, J. Douglas
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Physical
Abstract:High resolution spectroscopic studies of rovibrational state mixing in the ground electronic state of the molecules methyl glyoxal and methyl formate are presented. The technique of Stimulated Emission Pumping (SEP) spectroscopy is used to examine the effect of an intramolecular van der Waals interaction on intermode coupling of the carbonyl vibrational modes in methyl glyoxal. Rovibrational state mixing in the aldehyde CH stretching region of methyl formate is investigated by the technique of infrared fluorescence, utilizing a high resolution (0.001 cm$\sp{-1}$) Optical Parametric Oscillator to obtain fluorescence excitation spectra and dispersed fluorescence spectra of single molecular eigenstates.
Issue Date:1990
Type:Text
Language:English
URI:http://hdl.handle.net/2142/19080
Rights Information:Copyright 1990 Reid, Scott Allen
Date Available in IDEALS:2011-05-07
Identifier in Online Catalog:AAI9114381
OCLC Identifier:(UMI)AAI9114381


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