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 Title: Selective oxidation of aluminum bearing III-V semiconductors with applications to quantum well heterostructure lasers Author(s): Maranowski, Steven Andrew Doctoral Committee Chair(s): Holonyak, Nick, Jr. Department / Program: Electrical and Computer Engineering Discipline: Electrical Engineering Degree Granting Institution: University of Illinois at Urbana-Champaign Degree: Ph.D. Genre: Dissertation Subject(s): Engineering, Electronics and Electrical Engineering, Materials Science Abstract: In the present work, a water vapor oxidation process is used to convert high Al-composition $\rm Al\sb{x}Ga\sb{1-x}As\ and\ In\sb{0.5}(Al\sb{x}Ga\sb{1-x})\sb{0.5}P$ to stable, device-quality native oxides. The insulating and low-refractive-index properties of the native oxide prove useful in the fabrication of quantum well heterostructure laser diodes. The rate of oxide formation is sensitive to oxidation temperature and time, crystal doping, and, most dramatically the aluminum composition of the oxidizing layer. The higher aluminum composition semiconductors oxidize more readily.Selective oxidation of quantum well heterostructure crystals is used to convert only the highest aluminum composition materials to the native oxide. In the layered heterostructures commonly used in today's optoelectronic devices, selective oxidation is a unique way to "bury" an insulating and low-refractive-index oxide both above and below semiconductor layers used in a device. This makes possible, as described here, an edge-emitting laser diode that is confined both optically and electrically by "buried" oxide layers above and below the active region.Selective oxidation of $\rm Al\sb{x}Ga\sb{1-x}As$ occurs at low enough temperatures $(400\sp\circ$C-500$\sp\circ$C) to be performed on a fully metallized laser diode without adversely affecting its electrical performance. Metallized laser diodes are oxidized from their exposed facets, resulting in edge-emitting devices with current-blocking window regions at the mirrors. The buried oxide "spike," which extends from the facet into the crystal, forms selectively in a region of high aluminum composition. The buried oxide removes the current injection from the facet region, protects the facet, and results in improved maximum output powers from the lasers.Finally, the ability to form low-index $\rm(n\sim1.55)$ layers of oxide between high-index semiconductor crystals facilitates the formation of high-index-contrast distributed Bragg reflecting (DBR) mirrors. The properties of these mirrors and their applications to vertical cavity surface emitting lasers and edge-emitting lasers are described. Issue Date: 1995 Type: Text Language: English URI: http://hdl.handle.net/2142/19519 Rights Information: Copyright 1995 Maranowski, Steven Andrew Date Available in IDEALS: 2011-05-07 Identifier in Online Catalog: AAI9624427 OCLC Identifier: (UMI)AAI9624427
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