# Browse Abstracts & Presentations - 2014 International Symposium on Molecular Spectroscopy by Subject "Metal containing"

• (International Symposium on Molecular Spectroscopy, 2014-06-17)
A new electronic transition of molybdenum monoxide, MoO, was observed near 6735 \wn. Based upon recent ab initio calculations, the transition is tentatively assigned as the (0,0) band of the c$^{3}$$\Pi – b^{3}$$\Sigma$$^{-} ... application/vnd.openxmlformats-officedocument.presentationml.presentation Microsoft PowerPoint 2007 (4MB) • (International Symposium on Molecular Spectroscopy, 2014-06-17) We report mass spectra, 488 nm anion photoelectron spectra, and density functional theory (DFT) calculations of organometallic complexes produced by flow tube reactions of niobium with butadiene (C_{4}H_{6}), and compare ... application/vnd.openxmlformats-officedocument.presentationml.presentation Microsoft PowerPoint 2007 (2MB) • (International Symposium on Molecular Spectroscopy, 2014-06-17) \begin{wrapfigure}{r}{0pt} \includegraphics[scale=0.9]{NiONiO2.eps} \end{wrapfigure} Determining the physical properties (bond lengths, angles, dipole moments, etc) of transition metal oxides and dioxides is relevant ... application/vnd.openxmlformats-officedocument.presentationml.presentation Microsoft PowerPoint 2007 (3MB) • (International Symposium on Molecular Spectroscopy, 2014-06-17) The electronic transition spectrum of scandium monophosphide (ScP) molecule in the visible region between 480 nm and 550 nm has been recorded and analyzed using laser ablation/reaction free-jet expansion and laser induced ... application/vnd.openxmlformats-officedocument.presentationml.presentation Microsoft PowerPoint 2007 (1MB) • (International Symposium on Molecular Spectroscopy, 2014-06-17) The electronic transition spectrum of scandium monoxide (ScO) in the spectral region between 290 and 311 nm has been recorded using laser ablation/reaction free-jet expansion and laser induced fluorescence spectroscopy. ... application/vnd.openxmlformats-officedocument.presentationml.presentation Microsoft PowerPoint 2007 (1MB) • (International Symposium on Molecular Spectroscopy, 2014-06-17) High resolution infrared emission spectra of hot MgF_{2} in the 700 to 1300 cm^{-1} region have been recorded. The molecules were generated by heating solid MgF_{2} to 1675 ^{\circ}C. Four vibrational bands were ... application/vnd.openxmlformats-officedocument.presentationml.presentation Microsoft PowerPoint 2007 (14MB) • (International Symposium on Molecular Spectroscopy, 2014-06-17) The first spectroscopic study of rhenium carbide, ReC, has been performed using both low and high resolution techniques to collect rotationally resolved electronic spectra from 420 to 500nm. Laser-induced fluorescence ... application/vnd.openxmlformats-officedocument.presentationml.presentation Microsoft PowerPoint 2007 (5MB) • (International Symposium on Molecular Spectroscopy, 2014-06-17) Two laser-induced fluorescence techniques were used to access the high-lying C^{2}\Pi state (41242 \wn) in the metal-bearing molecule MgH. First, we directly excited the C^{2}\Pi state from the X^{2}\Sigma^{+} ground ... application/vnd.openxmlformats-officedocument.presentationml.presentation Microsoft PowerPoint 2007 (3MB) • (International Symposium on Molecular Spectroscopy, 2014-06-17) A rod of depleted uranium metal (mp = 1,132^{\circ} C) has been ablated with the fundamental operating frequency of a Nd:YAG laser. The resulting ablation plume of uranium was then mixed with argon gas and expanded ... application/vnd.openxmlformats-officedocument.presentationml.presentation Microsoft PowerPoint 2007 (4MB) • (International Symposium on Molecular Spectroscopy, 2014-06-17) A new electronic transition of PtF was observed by intracavity laser absorption spectroscopy. Based on the theoretical calculations of the electronic structure, this spectrum is assigned as the ^{2}$$\Sigma$$^{+} - ... application/vnd.openxmlformats-officedocument.presentationml.presentation Microsoft PowerPoint 2007 (2MB) • (International Symposium on Molecular Spectroscopy, 2014-06-17) Lanthanum hydride (\chem{LaH}) molecules were produced in a pulsed supersonic molecular beam by reaction of laser produced lanthanum metal plasma with \sim2\% ammonia seeded in helium gas. Rotationally resolved laser-induced ... application/vnd.openxmlformats-officedocument.presentationml.presentation Microsoft PowerPoint 2007 (997kB) • (International Symposium on Molecular Spectroscopy, 2014-06-17) The bonding and electrostatic properties of gold containing molecules are highly influenced by relativistic effects and electron correlation \footnote{P. Pyykko; \textit {Angew Chem. Int} {\textbf{43}} 4412, 2004.}. Hence ... application/vnd.openxmlformats-officedocument.presentationml.presentation Microsoft PowerPoint 2007 (2MB) • (International Symposium on Molecular Spectroscopy, 2014-06-17) The (0,0) band of the A^{2}$$\Pi$$_{3/2} - X^{2}$$\Sigma$$^{+}$ transition of ZrN is known to be perturbed. Both homogeneous and heterogeneous perturbations are observed in the spectrum. A recent high-level ab initio ...

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Microsoft PowerPoint 2007 (2MB)
• (International Symposium on Molecular Spectroscopy, 2014-06-17)
Gaseous $^{238}$UO was prepared in a high temperature furnace, and rotational spectra were measured in the 500--550 GHz and 590--650 GHz ranges. Transitions with $J$ from 24 to 32 were observed in the $\Omega=4$ ground ...

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Microsoft PowerPoint 2007 (2MB)
• (International Symposium on Molecular Spectroscopy, 2014-06-17)
\textit{Ab initio} calculations were employed to investigate M$^{+}$—RG$_{2}$ species. Trends in binding energies, \textit{D}$_{e}$, bond lengths, and bond angles are discussed and rationalised by analysing the electronic ...

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Microsoft PowerPoint 2007 (33MB)
• (International Symposium on Molecular Spectroscopy, 2014-06-17)
Accurate studies of the ground and low lying excited triplet pi-states of the covalently bonded alkaline earth metal carbides have been of interest to both theoreticians and experimentalists in the past few decades to ...

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Microsoft PowerPoint 2007 (5MB)