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Title:Stark And Zeeman Effect Study Of The [18.6]3.5 - X(1)4.5 Band Of Uranium Monofluoride, Uf.
Author(s):Linton, Colan
Contributor(s):Steimle, Timothy; Adam, Allan G.
Subject(s):Small molecules
Abstract:A high resolution spectrum of the [18.6]3.5 - X(1)4.5 band of UF was obtained using the laser ablation specrometer at Arizona State University (ASU). The rotational structure showed significant perturbations in the upper state. Examination of the Stark and Zeeman splittings of the lowest J lines in electric fields up to 3.4 kV/cm and a magnetic field of 1650 Gauss yielded permanent electric dipole moments, $\mu$$_{e}$, of 1.99 and 1.87 Debye and magnetic g-factors, g$_{e}$ of 3.28 and 3.26 for the ground and excited states respectively. The above experimental results will be discussed in terms of the configurational composition of the ground and excited states and compared with recent theoretical calculations\footnote{Ivan O. Antonov and Michael C. Heaven, J. Phys. Chem. A 2013, 117, 9684-9694}.
Issue Date:2014-06-16
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:Linton, C.; Steimle, T.; Adam, A.G. STARK AND ZEEMAN EFFECT STUDY OF THE [18.6]3.5 - X(1)4.5 BAND OF URANIUM MONOFLUORIDE, UF.. Proceedings of the International Symposium on Molecular Spectroscopy, Urbana, IL, June 16-21, 2014. DOI: 10.15278/isms.2014.MG08
Genre:Conference Paper / Presentation
Rights Information:Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License.
Date Available in IDEALS:2014-09-17

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