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 Title: Submillimeter Measurements Of The Criegee Intermediate, Ch2oo, In The Gas Phase Author(s): Daly, Adam M Contributor(s): Yu, Shanshan; Drouin, Brian Subject(s): Mini-symposium: Spectroscopy in Kinetics and Dynamics Abstract: High frequency pure rotational transitions of the simplest Criegee intermediate, methylene peroxide (CH2OO), have been measured up to 1 THz. The data provide the most accurate spectroscopic parameters for the ground vibrational state. The molecule was produced in a flow cell with a DC discharge of CH$_{2}$I$_{2}$, O$_{2}$ and Ar. Doppler limited measurements were made in the frequency ranges 220-320, 580-680 and 970-1080 GHz at room temperature. A total of 211 transitions were measured and added to four transitions measured in the microwave to obtain a fit up to J$^{max}$ = 49 and K$^{max}$ = 14 of the a-dipole spectrum. Issue Date: 2014-06-18 Publisher: International Symposium on Molecular Spectroscopy Citation Info: Daly, A.M.; Yu, S.; Drouin, B. SUBMILLIMETER MEASUREMENTS OF THE CRIEGEE INTERMEDIATE, CH2OO, IN THE GAS PHASE. Proceedings of the International Symposium on Molecular Spectroscopy, Urbana, IL, June 16-21, 2014. DOI: 10.15278/isms.2014.WH07 Genre: CONFERENCE PAPER/PRESENTATION Type: Text Language: English URI: http://hdl.handle.net/2142/50835 DOI: 10.15278/isms.2014.WH07 Rights Information: Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/ Date Available in IDEALS: 2014-09-172015-04-14
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