Files in this item

FilesDescriptionFormat

application/vnd.openxmlformats-officedocument.presentationml.presentation

application/vnd.openxmlformats-officedocument.presentationml.presentationRB12_Presentation.pptx (1MB)
PresentationMicrosoft PowerPoint 2007

application/pdf

application/pdfRB12_Abstract.pdf (15kB)
AbstractPDF

text/plain

text/plainRB12_Abstract.txt (1kB)
AbstractText file

Description

Title:Effect Of Substituents In Alcohol-amine Complexes
Author(s):Hansen, Anne Schou
Contributor(s):Kjærgaard, Henrik; Du, Lin
Subject(s):Clusters/Complexes
Abstract:\noindent A series of alcohol-amine complexes have been investigated to gain physical insight into the effect on the hydrogen bond strength as different substituents are attached. The series of complexes investigated are shown in the figure, \begin{wrapfigure}{o}{0pt} \includegraphics[scale=0.8]{structure-al-amine1.eps} \end{wrapfigure} \noindent where R$_1$ = CH$_3$, CH$_3$CH$_2$ or CF$_3$CH$_2$ and R$_2$ = H or CH$_3$. To estimate the hydrogen bond strength, redshifts of the OH-stretching transition frequency upon complexation were measured using gas phase Fourier Transform InfraRed (FTIR) spectroscopy. Equilibrium constants for the formation of the complexes were also determined, exploiting a combination of a calculated oscillator strength and the measured integrated absorbance of the fundamental OH-stretching and second overtone NH-stretching transitions.
Issue Date:2014-06-19
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:Hansen, A.S.; Kjærgaard, H.; Du, L. EFFECT OF SUBSTITUENTS IN ALCOHOL-AMINE COMPLEXES. Proceedings of the International Symposium on Molecular Spectroscopy, Urbana, IL, June 16-21, 2014. DOI: 10.15278/isms.2014.RB12
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/50899
DOI:10.15278/isms.2014.RB12
Rights Information:Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/
Date Available in IDEALS:2014-09-17
2015-04-14


This item appears in the following Collection(s)

Item Statistics