Files in this item
| Files | Description | Format |
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application/vnd.openxmlformats-officedocument.presentationml.presentation  RG09_Presentation.pptx (9MB) | Presentation | Microsoft PowerPoint 2007 |
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application/pdf  RG09_Abstract.pdf (17kB) | Abstract | |
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text/plain  RG09_Abstract.txt (750bytes) | Abstract | Text file |
Description
| Title: | Infrared Spectra Of Anionic Cobalt-carbon Dioxide Clusters |
| Author(s): | Weber, J. Mathias |
| Contributor(s): | Knurr, Benjamin |
| Subject(s): | Mini-symposium: Beyond the Mass-to-Charge Ratio: Spectroscopic Probes of the Structures of Ions |
| Abstract: | We present infrared photodissociation spectra of Co(CO$_2$)$_n^-$ ions ($n$ = 3 – 11) in the wavenumber region 1000 – 2400 cm$^{-1}$, interpreted with the aid of density functional theory calculations. The spectra show signatures of several structural motifs for the interaction of a Co atom and CO$_2$ ligands. The spectra are dominated by a core ion showing bidentate interaction of two CO$_2$ ligands forming C-Co and O-Co bonds. The prevalence of triplet vs singlet states and the charge distribution in the Co(CO$_2$)$_2^-$ core ion will also be discussed. |
| Issue Date: | 2014-06-19 |
| Publisher: | International Symposium on Molecular Spectroscopy |
| Citation Info: | Weber, J.M.; Knurr, B. INFRARED SPECTRA OF ANIONIC COBALT-CARBON DIOXIDE CLUSTERS. Proceedings of the International Symposium on Molecular Spectroscopy, Urbana, IL, June 16-21, 2014. DOI: 10.15278/isms.2014.RG09 |
| Genre: | CONFERENCE PAPER/PRESENTATION |
| Type: | Text |
| Language: | English |
| URI: | http://hdl.handle.net/2142/50912 |
| DOI: | 10.15278/isms.2014.RG09 |
| Rights Information: | Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/ |
| Date Available in IDEALS: | 2014-09-17 2015-04-14 |