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Title:Infrared Spectra Of Anionic Cobalt-carbon Dioxide Clusters
Author(s):Weber, J. Mathias
Contributor(s):Knurr, Benjamin
Subject(s):Mini-symposium: Beyond the Mass-to-Charge Ratio: Spectroscopic Probes of the Structures of Ions
Abstract:We present infrared photodissociation spectra of Co(CO$_2$)$_n^-$ ions ($n$ = 3 – 11) in the wavenumber region 1000 – 2400 cm$^{-1}$, interpreted with the aid of density functional theory calculations. The spectra show signatures of several structural motifs for the interaction of a Co atom and CO$_2$ ligands. The spectra are dominated by a core ion showing bidentate interaction of two CO$_2$ ligands forming C-Co and O-Co bonds. The prevalence of triplet vs singlet states and the charge distribution in the Co(CO$_2$)$_2^-$ core ion will also be discussed.
Issue Date:2014-06-19
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:Weber, J.M.; Knurr, B. INFRARED SPECTRA OF ANIONIC COBALT-CARBON DIOXIDE CLUSTERS. Proceedings of the International Symposium on Molecular Spectroscopy, Urbana, IL, June 16-21, 2014. DOI: 10.15278/isms.2014.RG09
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/50912
DOI:10.15278/isms.2014.RG09
Rights Information:Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/
Date Available in IDEALS:2014-09-17
2015-04-14


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