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Title:Impact Ft-mw Spectroscopy Of Organic Rings: Investigation Of The Conformational Landscape
Author(s):Wachsmuth, Dennis
Contributor(s):Lesarri, Alberto; Grabow, Jens-Uwe
Subject(s):Structure determination
Abstract:Organic rings are common building blocks in biologically active molecules. In contrast to six-membered rings, cycloalkanes with seven or more ring atoms have a less rigid structure which allows for conformational diversity and complex internal dynamics. The broadband \itshape in-phase/quadrature-phase-modulation passage-acquired-coherence technique \upshape (\mbox{IMPACT}) FT-microwave spectroscopy is the ideal experimental method to gain insight into the conformational freedom and structure of these cyclic motifs.\\ The combination of high spectral resolution ($<10$~kHz) and frequency accuracy with a 1~GHz wideband acquisition range per experimental pulse (over the entire $2$ to $26.5$~GHz range) makes the \mbox{IMPACT} spectrometer a time-saving tool when it comes to the investigation of fine or hyperfine effects and/or wide tunelling splittings. In this communication we will present the rotational spectra of several organic seven-membered rings, reporting on their conformational preferences and molecular structures.
Issue Date:2014-06-17
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:Wachsmuth, D.; Lesarri, A.; Grabow, J. IMPACT FT-MW SPECTROSCOPY OF ORGANIC RINGS: INVESTIGATION OF THE CONFORMATIONAL LANDSCAPE. Proceedings of the International Symposium on Molecular Spectroscopy, Urbana, IL, June 16-21, 2014. DOI: 10.15278/isms.2014.TE09
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/50972
DOI:10.15278/isms.2014.TE09
Rights Information:Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/
Date Available in IDEALS:2014-09-17
2015-04-14


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