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Title:Waveguide chipred-pulse fourier transform microwave spectroscopy of allyl bromide
Author(s):McCabe, Morgan N
Contributor(s):Shipman, Steven
Subject(s):Chirped pulse
Abstract:The rotational spectrum of allyl bromide was recorded from 8.7 to 26.5 GHz at -20 $^{\circ}$C with a waveguide chirped-pulse Fourier transform microwave spectrometer. The rotational spectrum of allyl bromide has been previously studied by Niide and coworkers. \footnote{Y.~Niide,~M,~Takano,T.~Satoh,~and Y.~Sasada~J.~Mol. Spectrosc., 63, 108(1976)}$^,$\footnote {Niide,~Yuzuru, J. Sci. Hiroshima Univ., Ser. A, 48, 1(1984)} However, previous assignments of this spectrum only extended to J = 12 and K$_a$ = 1. Newly acquired data from our spectrometer has allowed us to extend the previous work to higher values of J and K$_a$, leading to significant improvements in the distortion constants in particular. Comparisons between the spectra and conformational preferences of the allyl halides will also be discussed.
Issue Date:2014-06-19
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:McCabe, M.N.; Shipman, S. WAVEGUIDE CHIRPED-PULSE FOURIER TRANSFORM MICROWAVE SPECTROSCOPY OF ALLYL BROMIDE. Proceedings of the International Symposium on Molecular Spectroscopy, Urbana, IL, June 16-21, 2014. DOI: 10.15278/isms.2014.RE09
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/51006
DOI:10.15278/isms.2014.RE09
Rights Information:Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/
Date Available in IDEALS:2014-09-17
2015-04-14


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