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Title:Laboratory Detection Of Clznch3 (x1a1): Further Evidence For Zinc Insertion
Author(s):Bucchino, Matthew
Contributor(s):Ziurys, Lucy
Subject(s):Structure determination
Abstract:The pure rotational spectrum of methylzinc chloride, ClZnCH$_{3}$ (X$^{1}$A$_{1}$), has been recorded in the gas phase using direct absorption spectroscopic techniques. ClZnCH$_{3}$ was synthesized by the reaction of zinc vapor, generated in a Broida-type oven, with chloromethane in the presence of a DC discharge. Rotational transitions of the main isotopologue, $^{35}$Cl$^{64}$ZnCH$_{3}$, were measured in the frequency range of 260${-297}$ GHz. The presence of clear K-ladder structure (K = 0${-6}$) indicates that the species is a symmetric top with C$_{3V}$ symmetry. ClZnCH$_{3}$ appears to be formed by the oxidative addition of atomic zinc to chloromethane. Searches for the $^{37}$Cl, $^{66}$Zn, $^{13}$C, and D substituted isotopologues are currently in progress. The geometries of ClZnCH$_{3}$ and IZnCH$_{3}$ will be compared with reactivity trends for halogen-substituted organometallic reagents.
Issue Date:2014-06-18
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:Bucchino, M.; Ziurys, L. LABORATORY DETECTION OF ClZnCH3 (X1A1): FURTHER EVIDENCE FOR ZINC INSERTION. Proceedings of the International Symposium on Molecular Spectroscopy, Urbana, IL, June 16-21, 2014. DOI: 10.15278/isms.2014.WJ02
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/51014
DOI:10.15278/isms.2014.WJ02
Rights Information:Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/
Date Available in IDEALS:2014-09-17
2015-04-14


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