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Title:Vibrational states at the dissociation limit protected from vibrational energy flow
Author(s):Gruebele, Martin
Subject(s):Mini-symposium: Spectroscopy in Kinetics and Dynamics
Abstract:I will discuss the detection of sharp vibrational transitions with up to 40 quanta of total excitation above the dissociation limit of thiophosgene (SCCl$_2$). A 6-D CASSCF calculation and filtered diagonalization of eigenstates to compute dilution factors for bright states explains the 'survival' of these states and their expected number quantitatively.
Issue Date:2014-06-16
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:Gruebele, M. VIBRATIONAL STATES AT THE DISSOCIATION LIMIT PROTECTED FROM VIBRATIONAL ENERGY FLOW. Proceedings of the International Symposium on Molecular Spectroscopy, Urbana, IL, June 16-21, 2014. DOI: 10.15278/isms.2014.MH07
Genre:Conference Paper / Presentation
Type:Text
Language:English
URI:http://hdl.handle.net/2142/55878
DOI:10.15278/isms.2014.MH07
Rights Information:Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/
Date Available in IDEALS:2014-11-21
2015-04-14


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