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Title:Studies of Reaction Mechanisms Requiring Low Molecular Weight Thiol Cofactors
Author(s):Frick, Thomas Dennison
Department / Program:Biochemistry
Discipline:Biochemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Biochemistry
Abstract:The methyl-transfer reaction between methylcobalamin and 2-mercapto-ethanesulfonic acid (Coenzyme M) was investigated. We propose that this reaction is a thiyl radical promoted homolytic cleavage of the cobalt-carbon bond rather than the nucleophilic attack by thiolate anion which has been pro
Issue Date:1980
Type:Text
Language:English
Description:166 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1980.
URI:http://hdl.handle.net/2142/67402
Other Identifier(s):(UMI)AAI8108506
Date Available in IDEALS:2014-12-14
Date Deposited:1980


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