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Title:Calorimetry and Structure-Reactivity Relationships in Hypervalent Compounds of Phosphorus and Sulfur
Author(s):Ross, Michael Reiff
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:Phosphoranoxide 1, or its conjugate acid (10), TBP 10-P-5 species, hydrolyze to diol phosphinate 11 in boiling ethanolic KOH (72 hours); this reaction is reversed by treating 11 with aqueous HCl. Under these conditions, hydrolysis of isoelectronic-isostructural 10-S-5 sulfurane oxide 2b gave n
Issue Date:1981
Type:Text
Description:246 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1981.
URI:http://hdl.handle.net/2142/70169
Other Identifier(s):(UMI)AAI8203571
Date Available in IDEALS:2014-12-15
Date Deposited:1981


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