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Title:Preparation and Chemiluminescence of Cyclopropyl-Substituted Malonyl Peroxides
Author(s):Darmon, Michael John
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:4-Spiro{(2'-spirocyclopropyl)-cyclohexyl}-1,2-dioxolane-3,5-dione (2) and 4-cyclopropyl-4-methyl-1,2-dioxolane-3,5-dione (1) are prepared by the reaction of dicyclohexylcarbodiimide and hydrogen peroxide with the parent malonic acids. Chemiluminescence is observed when the cyclopropyl-substituted malonyl peroxides, 1 and 2, are heated in the presence of added aromatic fluorescers. The chemiluminescence is explained by the activated CIEEL mechanism with the aromatic fluorescer and malonyl peroxide. A cyclopropylcarbinyl-allylcarbinyl radical rearrangement is proposed to be involved in the chemiluminescence mechanism.
Issue Date:1982
Type:Text
Description:126 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1982.
URI:http://hdl.handle.net/2142/70187
Other Identifier(s):(UMI)AAI8218452
Date Available in IDEALS:2014-12-15
Date Deposited:1982


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