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Title:The Photochemistry of 3- and 4-Nitro Phenyl Azides
Author(s):Liang, Tsuei-Yun
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:The photochemistry of 4-nitro and 3-nitrophenyl azides in inert and reactive solvents was examined. Photolysis of nitrophenyl azides in solution at room temperature or in a frozen glass at 77 K gives triplet nitrenes. The products of the reaction of triplet nitrenes depend on the power of the light source. Triplet 4-nitrophenyl nitrene dimerizes to form azobenzene at a diffusion controlled rate and reacts with the tertiary amine by single-electron transfer. The rate constant of the reaction of triplet nitrenes with O$\sb2$ is ca. 10,000 fold slower than the dimerization. The precursors of the triplet nitrenes can be trapped by secondary amines. The mechanisms of these reactions are discussed.
Issue Date:1987
Type:Text
Description:159 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1987.
URI:http://hdl.handle.net/2142/70372
Other Identifier(s):(UMI)AAI8721692
Date Available in IDEALS:2014-12-15
Date Deposited:1987


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