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Title:ROTATIONALLY RESOLVED SPECTROSCOPY OF THE B1__ X1_+ AND C1_+_ X1_+ ELECTRONIC BANDS OF CaO
Author(s):Sullivan, Michael
Contributor(s):Heaven, Michael; Stewart, Jacob
Subject(s):Metal containing
Abstract:The $B^{1}Pileftarrow X^{1}Sigma^{+}$ and $C^{1}Sigma^{+}leftarrow X^{1}Sigma^{+}$ transitions of CaO, at energies below 30,000 $mathrm{cm^{-1}}$, were previously investigated by Lagerqvistfootnote{A. Lagerqvist, textit{Arkiv F{\"o}r Fysik} textbf{underline{8}}, 83, 1954}. The arc source used in that work yielded spectra at energies above 30,000 $mathrm{cm^{-1}}$ that were too congested for analysis. In the present study we have used jet-cooling of CaO to extend the characterization of the $Bleftarrow X$ and $Cleftarrow X$ band systems up to 35,000 $mathrm{cm^{-1}}$. Analyses of these data and spectroscopic constants will be reported. This work is being carried out in support of two-color photoionization studies of the cation, where the higher energy vibronic levels of the B and C states are used as the first excitation step.
Issue Date:23-Jun-15
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:ACS
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/79144
Date Available in IDEALS:2016-01-05


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