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Title:MICROWAVE SPECTRUM, VAN DER WAALS BOND LENGTH, AND 131Xe QUADRUPOLE COUPLING CONSTANT OF Xe-SO3
Author(s):Huff, Anna
Contributor(s):Leopold, Ken; Mackenzie, Becca; Dewberry, Chris
Subject(s):Clusters/Complexes
Abstract:Nine isotopologues of Xe-SO$_{3}$ have been observed by pulsed-nozzle Fourier transform microwave spectroscopy. The complex is a symmetric top with a Xe-S van der Waals distance of 3.577(2) {AA}. The increase in rare gas distance relative to that in Kr-SO$_{3}$ is equal to the difference in van der Waals radii between Xe and Kr. The $^{131}$Xe nuclear quadrupole coupling constant indicates that the electric field gradient at the xenon nucleus is 78% larger than that at the Kr nucleus in Kr-SO$_{3}$.
Issue Date:25-Jun-15
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:ACS
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/79262
Date Available in IDEALS:2016-01-05


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