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Title:REACTIONS OF 3-OXETANONE AT HIGH TEMPERATURES
Author(s):McCunn, Laura R.
Contributor(s):Urness, Kimberly N.; Foreman, Hannah; Warner, Brian; Wright, Emily
Subject(s):Spectroscopy as an analytical tool
Abstract:The pyrolysis of 3-oxetanone, O(CH$_{2}$)$_{2}$CO, has been studied in a resistively heated SiC tubular reactor at 400-1200$ ^{circ}$C. Products of pyrolysis were identified via matrix-isolation FTIR spectroscopy and photoionization mass spectrometry in separate experiments. While 3-oxetanone is expected to dissociate into ketene and formaldehyde, these experiments show that ethylene oxide and carbon monoxide are also produced. Methyl radical and ethylene were observed as additional products and are thought to be the result of reactions involving ethylene oxide.
Issue Date:26-Jun-15
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:ACS
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/79285
Date Available in IDEALS:2016-01-05


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