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Title:VELOCITY MAP IMAGING STUDY OF THE PHOTOINITIATED CHARGE-TRANSFER DISSOCIATION OF Cu+(C6H6) AND Ag+(C6H6)
Author(s):Maner, Jon
Contributor(s):Duncan, Michael A; Mauney, Daniel
Subject(s):Instrument/Technique Demonstration
Abstract:M$^{+}$(C$_{6}$H$_{6}$) (M = Cu, Ag) complexes are generated in the gas phase by laser vaporization and detected in a reflectron time-of-flight mass spectrometer. Excitation of M$^{+}$(C$_{6}$H$_{6}$) at 355 nm results exclusively in dissociative charge transfer, leading to neutral M and C$_{6}$H$_{6}$$^{+}$ products for both Cu and Ag complexes. Kinetic energy release in translationally hot C$_{6}$H$_{6}$$^{+}$ fragments is detected using a new apparatus designed for photofragment imaging of mass-selected ion beams. Velocity map imaging and slice imaging techniques are employed. Analysis of the data provide new information on the binding energies of Cu$^{+}$(C$_{6}$H$_{6}$) and Ag$^{+}$(C$_{6}$H$_{6}$).
Issue Date:25-Jun-15
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:ACS
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/79348
Date Available in IDEALS:2016-01-05


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