Files in this item

FilesDescriptionFormat

application/vnd.openxmlformats-officedocument.presentationml.presentation

application/vnd.openxmlformats-officedocument.presentationml.presentation482238.pptx (1MB)
PresentationMicrosoft PowerPoint 2007

application/pdf

application/pdf1314.pdf (17kB)
AbstractPDF

Description

Title:GENERATION OF VIBRATIONALLY EXCITED HCP FROM A STABLE SYNTHETIC PRECURSOR
Author(s):Hull, Alexander W.
Contributor(s):Field, Robert W; Cummins, Christopher; Nava, Matthew; Womack, Carrie; Erickson, Trevor J.; Jiang, Jun
Subject(s):Small molecules
Abstract:HCP belongs to a class of reactive small molecules with much interest to spectroscopists. It bears certain similarities to HCN, including a strong ~{A}(bent) - ~{X}(linear) ultraviolet transition, associated with the HCP-HPC isomerization pathway. HCP has traditionally been generated by the $in situ$ reaction of chem{PH_3} and acetylene. In this talk, we will discuss a recently developed synthetic precursor molecule, 1,1-((triphenylphosphoranylidene)methyl)-9,10-phosphanoanthracene. At temperatures above 200 degrees Celsius, this precursor is thought to release HCP in a vibrationally excited state. We will present preliminary spectra on this system obtained by LIF and chirped pulse millimeter wave spectroscopy.
Issue Date:22-Jun-15
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:ACS
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/79391
Date Available in IDEALS:2016-01-05


This item appears in the following Collection(s)

Item Statistics