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Title:FORMATION OF M-C _ C-Cl (M = Ag or Cu) AND CHARACTERIZATION BY ROTATIONAL SPECTROSCOPY
Author(s):Zaleski, Daniel P.
Contributor(s):Legon, Anthony; Walker, Nick; Tew, David Peter
Subject(s):Metal containing
Abstract:The new linear molecule Ag-C$equiv$C-Cl has been detected and characterized by means of rotational spectroscopy. It was synthesized by laser ablation of a silver rod in the presence of a gaseous sample containing a low concentration of CCl$_{4}$ in argon, cooled to a rotational temperature approaching 2 K through supersonic expansion and analyzed by chirped pulse Fourier transform microwave spectroscopy. Substitution coordinates are available for the silver and chlorine positions and will be compared to ab initio calculations at the CCSD(T)/aug-cc-pV5Z level of theory. The Ag-$^{13}$C$equiv$$^{13}$C-Cl isotopologue was also observed using a similar gas mixture containing $^{13}$CCl$_{4}$. The Cu analogue Cu-C$equiv$C-Cl was similarly identified and characterized.
Issue Date:25-Jun-15
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:ACS
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/79431
Date Available in IDEALS:2016-01-05


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