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Title:Utilization of Rationally Designed Small Molecule Chiral Selectors in Novel Enantioselective Processes
Author(s):Snyder, Seth Elliot
Doctoral Committee Chair(s):Pirkle, William H.
Department / Program:Chemical Engineering
Discipline:Chemical Engineering
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:In addition, phase transfer catalyzed biphasic kinetic resolutions of several racemic amides containing electron-deficient aromatic moieties are described. The method revolves around forming Meisenheimer adducts which are stabilized by quaternary ammonium salts in a nonpolar medium. When run in the presence of a chiral selector, one enantiomer is effectively shielded from reaction. The methodology is extended to enantioselective nucleophilic aromatic substitution, reactions known to proceed through the intermediacy of a Meisenheimer adduct.
Issue Date:2003
Type:Text
Language:English
Description:133 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2003.
URI:http://hdl.handle.net/2142/82349
Other Identifier(s):(MiAaPQ)AAI3086180
Date Available in IDEALS:2015-09-25
Date Deposited:2003


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