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Title:Processing Effects for Integrated PZT: Residual Stress, Thickness, and Dielectric Properties
Author(s):Ong, Ryan Jason
Doctoral Committee Chair(s):Payne, David A.
Department / Program:Materials Science and Engineering
Discipline:Materials Science and Engineering
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Engineering, Materials Science
Abstract:A series-capacitor model accounted for the observed dilution in room-temperature K from >900 to ∼600 as film thickness decreased, but could not account for the absence of the expected dielectric anomaly at high temperatures. Instead, a stress-induced distributed phase transformation related to the polycrystalline nature of the film was proposed to account for the observed behavior. Residual stress reduced the spontaneous polarization values in these specimens to 32muC/cm 2 from the predicted stress-free value of 50muC/cm2. An increase in coercive field was attributed to interfacial capacitance and residual stress, whereas a decrease of 30MPa tensile stress resulted in an increase of d33 from 33 to 65pm/V, irrespective of changes in film thickness. These results isolated, for the first time, the effects of stress and thickness on the dielectric, ferroelectric and piezoelectric properties of PZT films without convolution from the other major variables. The research provides a guideline for the tailoring of properties by modifying mechanical stress in polarizable and deformable thin films.
Issue Date:2005
Type:Text
Language:English
Description:162 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2005.
URI:http://hdl.handle.net/2142/82764
Other Identifier(s):(MiAaPQ)AAI3182340
Date Available in IDEALS:2015-09-25
Date Deposited:2005


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