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Title:Cored Dendrimers: Synthesis and Applications
Author(s):Wendland, Michael Scott
Doctoral Committee Chair(s):Zimmerman, Steven C.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:Analogous to molecular imprinted polymers, cored dendrimers were imprinted by synthesizing the structure in the presence of a template (core unit). Porphyrins were found to be useful target compounds for which to imprint cored dendrimers. The porphyrins were used as spectrophotometric probes to determine the selectivity of the cored dendrimer. Binding studies with various functionalized porphyrins and the cored dendrimer were monitored by UV/Vis spectroscopy. The results showed that these cored dendrimers were selective for porphyrins complementary in both shape and functionality to the binding site created in their interior. The binding behavior of these cored dendrimers was found to be sensitive to the conditions used for the cross-linking reaction.
Issue Date:2001
Type:Text
Language:English
Description:188 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2001.
URI:http://hdl.handle.net/2142/84031
Other Identifier(s):(MiAaPQ)AAI3017250
Date Available in IDEALS:2015-09-25
Date Deposited:2001


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