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Description
Title: | Synthesis and Characterization of Organometallic Cyanides and Phthalocyanines |
Author(s): | Contakes, Stephen Myron |
Doctoral Committee Chair(s): | Rauchfuss, Thomas B. |
Department / Program: | Chemistry |
Discipline: | Chemistry |
Degree Granting Institution: | University of Illinois at Urbana-Champaign |
Degree: | Ph.D. |
Genre: | Dissertation |
Subject(s): | Chemistry, Inorganic |
Abstract: | pi-arene complexes of octaalkoxyphthalocyanines and metallophthalocyanines were prepared by reaction of soluble phthalocyanine (H2PcOR) and metallophthalocyanine (M(PcOR)) ligands with Cp*Ru(NCMe)3 +. The molecular structure of {Cp*Ru[eta6-Ni(PcOBu)]}PF 6 consists of a dimer of two cofacially stacked {Cp*Ru[eta 6-Ni(PcOBu)]}+ units. In [Cp*Ru(eta6-H 2PcOEt)]PF6 the two NH protons exhibit differences in reactivity, and the N4H2 pocket can be metallated. |
Issue Date: | 2001 |
Type: | Text |
Language: | English |
Description: | 221 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2001. |
URI: | http://hdl.handle.net/2142/84034 |
Other Identifier(s): | (MiAaPQ)AAI3023036 |
Date Available in IDEALS: | 2015-09-25 |
Date Deposited: | 2001 |
This item appears in the following Collection(s)
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Dissertations and Theses - Chemistry
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Graduate Dissertations and Theses at Illinois
Graduate Theses and Dissertations at Illinois