Synthesis and Characterization of Organometallic Cyanides and Phthalocyanines

Contakes, Stephen Myron
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Title:Synthesis and Characterization of Organometallic Cyanides and Phthalocyanines
Author(s):Contakes, Stephen Myron
Doctoral Committee Chair(s):Rauchfuss, Thomas B.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:pi-arene complexes of octaalkoxyphthalocyanines and metallophthalocyanines were prepared by reaction of soluble phthalocyanine (H2PcOR) and metallophthalocyanine (M(PcOR)) ligands with Cp*Ru(NCMe)3 +. The molecular structure of {Cp*Ru[eta6-Ni(PcOBu)]}PF 6 consists of a dimer of two cofacially stacked {Cp*Ru[eta 6-Ni(PcOBu)]}+ units. In [Cp*Ru(eta6-H 2PcOEt)]PF6 the two NH protons exhibit differences in reactivity, and the N4H2 pocket can be metallated.
Issue Date:2001
Type:Text
Language:English
Description:221 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2001.
URI:http://hdl.handle.net/2142/84034
Other Identifier(s):(MiAaPQ)AAI3023036
Date Available in IDEALS:2015-09-25
Date Deposited:2001


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