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Title:Porphyrin Network Materials: Chemical Exploration in the Supramolecular Solid-State
Author(s):Kosal, Margaret Elizabeth
Doctoral Committee Chair(s):Kenneth S. Suslick
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Engineering, Materials Science
Abstract:The large internal cavities of PIZA-1 are a consequence of the trinuclear Co(II)carboxylate cluster forcing the ruffling of the porphyrin building blocks. The linear trinuclear metal-carboxylate cluster of PIZA-1 is contrasted with the bent trinuclear M(II) carboxylate clusters (M = Co, Mn) of isostructural 3-dimensional frameworks: PIZA-2 and PIZA-3. Containing near-planar metalloporphyrin macrocycles, PIZA-2 and PIZA-3 manifest lower void volumes (56%).
Issue Date:2001
Type:Text
Language:English
Description:273 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2001.
URI:http://hdl.handle.net/2142/84043
Other Identifier(s):(MiAaPQ)AAI3023099
Date Available in IDEALS:2015-09-25
Date Deposited:2001


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