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Title:Supramolecular Porphyrin Assemblies: Photosynthetic Reaction Center Analogs and Porphyrin Networks
Author(s):Paterno, Alicia Ann
Doctoral Committee Chair(s):Girolami, Gregory S.; Kenneth S. Suslick
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:Photophysical measurements were carried out in collaboration with Professor Dewey Holten and Robin Lammi at Washington University. The lifetimes for the initial photoexcited states of the triad, protected triad, and Zr(TTP)(TTP-NH 2) in a given solvent are the same within experimental error. This result means that an electron is not transferring to the monomeric spacer porphyrin in high yield. Presumably, the DeltaG for this process is too unfavorable. Instead, the excited zirconium bis(porphyrin) sandwich complex simply returns to the ground state. One way to improve upon this system would be to make the bridging porphyrin a better electron acceptor by replacing the mesityl substituents with pentafluorophenyl groups.
Issue Date:2001
Type:Text
Language:English
Description:212 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2001.
URI:http://hdl.handle.net/2142/84049
Other Identifier(s):(MiAaPQ)AAI3023168
Date Available in IDEALS:2015-09-25
Date Deposited:2001


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