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Title:Reaction of Aqueous Polyoxometalates With Silver and Gold Surfaces
Author(s):Powell, Jason Daniel
Doctoral Committee Chair(s):Klemperer, Walter G.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:Preliminary experiments to study the reaction of acidic aqueous solutions of the Preyssler anion, NaP5W30O110 14-, with Ag(111) show that a surface phase is formed. Immersion of Au(111) in the same solutions yielded STM images that did not show evidence of a surface phase. By using a mixture of alpha-PVW11O40 4- and NaP5W30O110 14- in acidic aqueous solution, the terrace size of the surface phase formed on Ag(111) increased and its translational order improved.
Issue Date:2001
Type:Text
Language:English
Description:191 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2001.
URI:http://hdl.handle.net/2142/84050
Other Identifier(s):(MiAaPQ)AAI3023174
Date Available in IDEALS:2015-09-25
Date Deposited:2001


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