The Structure of Solvents Confined to Metal Surfaces

Si, Siv Keng
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Title:The Structure of Solvents Confined to Metal Surfaces
Author(s):Si, Siv Keng
Doctoral Committee Chair(s):Gewirth, Andrew A.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Analytical
Abstract:Finally, tetrabutylammonium perchlorate (TBAP) is added to DMSO. Under potential control, positive of the potential of zero charge (PZC), STM reveals the DMSO solvent structure together with the perchlorate anion. The tetrabutylammoniurn cation can not be seen due to the presence of water in the DMSO solution. With appropriate choice of electrolyte, it may now be possible, by means of in situ STM, to examine the interplay of solvent, anion, and cation at the solid/liquid interface.
Issue Date:2001
Type:Text
Language:English
Description:85 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2001.
URI:http://hdl.handle.net/2142/84053
Other Identifier(s):(MiAaPQ)AAI3023196
Date Available in IDEALS:2015-09-25
Date Deposited:2001


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