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Description
Title: | The Structure of Solvents Confined to Metal Surfaces |
Author(s): | Si, Siv Keng |
Doctoral Committee Chair(s): | Gewirth, Andrew A. |
Department / Program: | Chemistry |
Discipline: | Chemistry |
Degree Granting Institution: | University of Illinois at Urbana-Champaign |
Degree: | Ph.D. |
Genre: | Dissertation |
Subject(s): | Chemistry, Analytical |
Abstract: | Finally, tetrabutylammonium perchlorate (TBAP) is added to DMSO. Under potential control, positive of the potential of zero charge (PZC), STM reveals the DMSO solvent structure together with the perchlorate anion. The tetrabutylammoniurn cation can not be seen due to the presence of water in the DMSO solution. With appropriate choice of electrolyte, it may now be possible, by means of in situ STM, to examine the interplay of solvent, anion, and cation at the solid/liquid interface. |
Issue Date: | 2001 |
Type: | Text |
Language: | English |
Description: | 85 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2001. |
URI: | http://hdl.handle.net/2142/84053 |
Other Identifier(s): | (MiAaPQ)AAI3023196 |
Date Available in IDEALS: | 2015-09-25 |
Date Deposited: | 2001 |
This item appears in the following Collection(s)
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Dissertations and Theses - Chemistry
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Graduate Dissertations and Theses at Illinois
Graduate Theses and Dissertations at Illinois