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Description
Title: | Synthesis and Maldi-Ms Characterization of New Ruthenium Sulfide Clusters |
Author(s): | Eckermann, Amanda Lorraine |
Doctoral Committee Chair(s): | Rauchfuss, Thomas B. |
Department / Program: | Chemistry |
Discipline: | Chemistry |
Degree Granting Institution: | University of Illinois at Urbana-Champaign |
Degree: | Ph.D. |
Genre: | Dissertation |
Subject(s): | Chemistry, Inorganic |
Abstract: | Finally, ruthenium sulfide phosphine nitrosyl clusters resulting from the reaction of RuCl3(NO)(P(aryl)3)2 and S(TMS)2 were investigated. The distorted heterocubane Ru4 S4(NO)4(PPh3)3 was crystallographically characterized and a related cluster with formula Ru4S3(NO) 4(PPh3)3, possibly corresponding to a partial heterocubane structure, was identified using MALDI-MS and IR spectroscopy. |
Issue Date: | 2002 |
Type: | Text |
Language: | English |
Description: | 168 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2002. |
URI: | http://hdl.handle.net/2142/84067 |
Other Identifier(s): | (MiAaPQ)AAI3069989 |
Date Available in IDEALS: | 2015-09-25 |
Date Deposited: | 2002 |
This item appears in the following Collection(s)
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Dissertations and Theses - Chemistry
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Graduate Dissertations and Theses at Illinois
Graduate Theses and Dissertations at Illinois