Synthesis and Maldi-Ms Characterization of New Ruthenium Sulfide Clusters

Eckermann, Amanda Lorraine
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Title:Synthesis and Maldi-Ms Characterization of New Ruthenium Sulfide Clusters
Author(s):Eckermann, Amanda Lorraine
Doctoral Committee Chair(s):Rauchfuss, Thomas B.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:Finally, ruthenium sulfide phosphine nitrosyl clusters resulting from the reaction of RuCl3(NO)(P(aryl)3)2 and S(TMS)2 were investigated. The distorted heterocubane Ru4 S4(NO)4(PPh3)3 was crystallographically characterized and a related cluster with formula Ru4S3(NO) 4(PPh3)3, possibly corresponding to a partial heterocubane structure, was identified using MALDI-MS and IR spectroscopy.
Issue Date:2002
Type:Text
Language:English
Description:168 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2002.
URI:http://hdl.handle.net/2142/84067
Other Identifier(s):(MiAaPQ)AAI3069989
Date Available in IDEALS:2015-09-25
Date Deposited:2002


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