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Title:Interactions of Nitrated Aromatics With Electron Rich Species: Chiral and Achiral
Author(s):Shvets, Aleksey
Doctoral Committee Chair(s):Pirkle, William H.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:The work described in Chapter 6 is of a mechanistic nature. Identification of the formation of Meisenheimer complexes under conditions of phase transfer catalysis helped to rationalize the enantioselectivity observed in these systems. Quaternary ammonium cations are identified as stabilizing factors for the negatively charged Meisenheimer complexes in non-polar organic solvents. The gained mechanistic insight allowed the development of the first enantioselective nucleophilic aromatic substitution reactions.
Issue Date:2002
Type:Text
Language:English
Description:104 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2002.
URI:http://hdl.handle.net/2142/84072
Other Identifier(s):(MiAaPQ)AAI3070049
Date Available in IDEALS:2015-09-25
Date Deposited:2002


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