(-)-Sparteine Mediated Lithiation of N-Boc-N-P-(methoxyphenyl) Allylic Amines and Conjugate Addition to Nitroalkenes: Scope, Reaction Pathway, and Synthetic Applications

Johnson, Timothy Allen
Use this link to cite this item:
http://hdl.handle.net/2142/84080

Files in this item

FilesDescriptionFormat

application/pdf

application/pdf3070342.pdf (10MB)Restricted to U of Illinois		(no description provided)PDF

Description

Title:(-)-Sparteine Mediated Lithiation of N-Boc-N-P-(methoxyphenyl) Allylic Amines and Conjugate Addition to Nitroalkenes: Scope, Reaction Pathway, and Synthetic Applications
Author(s):Johnson, Timothy Allen
Doctoral Committee Chair(s):Beak, Peter
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:The enecarbamate products of the conjugate additions may also be easily elaborated to enantioenriched functionalized cyclopentanoids. Hydrolysis of the enecarbamates followed by intramolecular nitro-aldol cyclization and dehydration provides substituted nitrocyclopentenes that were converted to substituted cyclopentanones and cyclopentylamines.
Issue Date:2002
Type:Text
Language:English
Description:267 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2002.
URI:http://hdl.handle.net/2142/84080
Other Identifier(s):(MiAaPQ)AAI3070342
Date Available in IDEALS:2015-09-25
Date Deposited:2002


This item appears in the following Collection(s)

Item Statistics