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Description
Title: | (-)-Sparteine Mediated Lithiation of N-Boc-N-P-(methoxyphenyl) Allylic Amines and Conjugate Addition to Nitroalkenes: Scope, Reaction Pathway, and Synthetic Applications |
Author(s): | Johnson, Timothy Allen |
Doctoral Committee Chair(s): | Beak, Peter |
Department / Program: | Chemistry |
Discipline: | Chemistry |
Degree Granting Institution: | University of Illinois at Urbana-Champaign |
Degree: | Ph.D. |
Genre: | Dissertation |
Subject(s): | Chemistry, Organic |
Abstract: | The enecarbamate products of the conjugate additions may also be easily elaborated to enantioenriched functionalized cyclopentanoids. Hydrolysis of the enecarbamates followed by intramolecular nitro-aldol cyclization and dehydration provides substituted nitrocyclopentenes that were converted to substituted cyclopentanones and cyclopentylamines. |
Issue Date: | 2002 |
Type: | Text |
Language: | English |
Description: | 267 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2002. |
URI: | http://hdl.handle.net/2142/84080 |
Other Identifier(s): | (MiAaPQ)AAI3070342 |
Date Available in IDEALS: | 2015-09-25 |
Date Deposited: | 2002 |
This item appears in the following Collection(s)
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Dissertations and Theses - Chemistry
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Graduate Dissertations and Theses at Illinois
Graduate Theses and Dissertations at Illinois