Tetrathiometallates in Synthesis and Catalysis

Schwarz, Daniel Eugene

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Title:	Tetrathiometallates in Synthesis and Catalysis
Author(s):	Schwarz, Daniel Eugene
Doctoral Committee Chair(s):	Rauchfuss, Thomas B.
Department / Program:	Chemistry
Discipline:	Chemistry
Degree Granting Institution:	University of Illinois at Urbana-Champaign
Degree:	Ph.D.
Genre:	Dissertation
Subject(s):	Chemistry, Inorganic
Abstract:	Finally, Et4N[ReS4] has also been shown to react with isocyanides (MeNC, t-BuNC, CyNC) which add across the S=M=S functionality via a 3+1 cycloaddition process in the presence of S 8 to form Et4N[Re(S)(S4)(S2CNR)]. This type of cycloaddition has not been observed before for metal sulfides.
Issue Date:	2003
Type:	Text
Language:	English
Description:	142 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2003.
URI:	http://hdl.handle.net/2142/84107
Other Identifier(s):	(MiAaPQ)AAI3086176
Date Available in IDEALS:	2015-09-25
Date Deposited:	2003