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Title:Synthesis and Reactivity of ruthenium(VI) and osmium(VI) Nitrido and Imido Complexes
Author(s):Lutz, Christopher Michael
Doctoral Committee Chair(s):Shapley, Patricia A.; Shapley, John R.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:Reaction of [N(n-Bu)4][M(N)Me4] with Me3SiOSO2CF3 yielded the neutral complexes Os(NSiMe3)Me4 and Ru(NSiMe3)Me4. These complexes reacted with water to generate Me3SiOH, CH 4, (Me3Si)2O and insoluble metal-containing species. Both reacted with carbon monoxide to form acetone derived from the alkyl ligands. Neither complex reacted with styrene. Trialkyl- and triarylphosphines trapped decomposition products and formed new compounds including Os(N)(PPh3 )Me3 and Os(N)(PMe3)Me3. Mixtures of Os(NSiMe3)Me4, styrene, and N-tosyliminophenyliodinane produced some nitrogen transfer product, cyclo-(tosyl)NCH 2CHPh.
Issue Date:2004
Type:Text
Language:English
Description:142 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2004.
URI:http://hdl.handle.net/2142/84136
Other Identifier(s):(MiAaPQ)AAI3130974
Date Available in IDEALS:2015-09-25
Date Deposited:2004


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